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An efficient copper-catalyzed carbenoid insertion reaction of α-diazo carbonyl compounds into si–h and s–h bonds was developed a wide. The inferred isotope ratios in comet lovejoy are 16o/18o = 499 ± 24 and d/h = 14 ± 04 × 10-4 in water, 32s/34s = 247 ± 35 in cs,. Rathgeber j(1), schorn b, falk v, kazmaier s, spiegel t, burchardi h assist/ controlled mandatory ventilation (s-cmv, 123 patients), synchronized intermittent .